Pressure-broadened Atomic Li(2s-2p) Line Perturbed By Ground Neon Atoms In The Spectral Wings And Core
Résumé: Full quantum calculations are performed to investigate the broadening profiles of the atomic lithium Li(2s-2p) resonance line induced by interactions with ground Ne(2s22p6)perturbers in the spectral wings and core. The X2S+, A2P,and B2S+ potential-energy curves of the two first low lying LiNe molecular states, as well as the corresponding transition dipole moments, are determined with ab initio methods based on the SA-CASSCF-MRCI calculations. The emission and absorption coefficients in the wavelength range 550–800 nm and the line-core width and shift are investigated theoretically for temperatures ranging from 130 K to 3000 K. Their temperature dependence is analyzed, and the obtained results are compared with the previous experimental measurements and theoretical works.
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